A team led by Nanfang Yu, assistant professor of applied physics at Columbia Engineering, has discovered a new phase-transition optical material and demonstrated novel devices that dynamically control light over a much broader wavelength range and with larger modulation amplitude than what has currently been possible.
The team, including researchers from Purdue, Harvard, Drexel, and Brookhaven National Laboratory, found that samarium nickelate (SmNiO3) can be electrically tuned continuously between a transparent and an opaque state over an unprecedented broad range of spectrum from the blue in the visible (wavelength of 400 nm) to the thermal radiation spectrum in the mid-infrared (wavelength of a few tens of micrometers). The study, which is the first investigation of the optical properties of SmNiO3 and the first demonstration of the material in photonic device applications, is published online today in Advanced Materials.
“The performance of SmNiO3 is record-breaking in terms of the magnitude and wavelength range of optical tuning,” Yu says. “There is hardly any other material that offers such a combination of properties that are highly desirable for optoelectronic devices. The reversible tuning between the transparent and opaque states is based on electron doping at room temperature, and potentially very fast, which opens up a wide range of exciting applications, such as ‘smart windows’ for dynamic and complete control of sunlight, variable thermal emissivity coatings for infrared camouflage and radiative temperature control, optical modulators, and optical memory devices.”
Some of the potential new functions include using SmNiO3‘s capability in controlling thermal radiation to build “intelligent” coatings for infrared camouflage and thermoregulation. These coatings could make people and vehicles, for example, appear much colder than they actually are and thus indiscernible under a thermal camera at night. The coating could help reduce the large temperature gradients on a satellite by adjusting the relative thermal radiation from its bright and dark side with respect to the sun and thereby prolong the lifetime of the satellite. Because this phase-transition material can potentially switch between the transparent and opaque states with high speed, it may be used in modulators for free-space optical communication and optical radar and in optical memory devices.
Researchers have long been trying to build active optical devices that can dynamically control light. These include Boeing 787 Dreamliner’s “smart windows,” which control (but not completely) the transmission of sunlight, rewritable DVD discs on which we can use a laser beam to write and erase data, and high-data-rate, long-distance fiber optic communications systems where information is “written” into light beams by optical modulators. Active optical devices are not more common in everyday life, however, because it has been so difficult to find advanced actively tunable optical materials, and to design proper device architectures that amplify the effects of such tunable materials.
When Shriram Ramanathan, associate professor of materials science at Harvard, discovered SmNiO3‘s giant tunable electric resistivity at room temperature, Yu took note. The two met at the IEEE Photonics Conference in 2013 and decided to collaborate. Yu and his students, working with Ramanathan, who is a co-author of this paper, conducted initial optical studies of the phase-transition material, integrated the material into nanostructured designer optical interfaces—“metasurfaces”—and created prototype active optoelectronic devices, including optical modulators that control a beam of light, and variable emissivity coatings that control the efficiency of thermal radiation.
“SmNiO3is really an unusual material,” says Zhaoyi Li, the paper’s lead author and Yu’s PhD student, “because it becomes electrically more insulating and optically more transparent as it is doped with more electrons—this is just the opposite of common materials such as semiconductors.”
It turns out that doped electrons “lock” into pairs with the electrons initially in the material, a quantum mechanical phenomenon called “strong electron correlation,” and this effect makes these electrons unavailable to conduct electric current and absorbing light. So, after electron doping, SmNiO3 thin films that were originally opaque suddenly allow more than 70 percent of visible light and infrared radiation to transmit through.
“One of our biggest challenges,” Zhaoyi adds, “was to integrate SmNiO3 into optical devices. To address this challenge, we developed special nanofabrication techniques to pattern metasurface structures on SmNiO3 thin films. In addition, we carefully chose the device architecture and materials to ensure that the devices can sustain high temperature and pressure that are required in the fabrication process to activate SmNiO3.”
Yu and his collaborators plan next to run a systematic study to understand the basic science of the phase transition of SmNiO3 and to explore its technological applications. The team will investigate the intrinsic speed of phase transition and the number of phase-transition cycles the material can endure before it breaks down. They will also work on addressing technological problems, including synthesizing ultra-thin and smooth films of the material and developing nanofabrication techniques to integrate the material into novel flat optical devices.
“This work is one crucial step towards realizing the major goal of my research lab, which is to make an optical interface a functional optical device,” Yu notes. “We envision replacing bulky optical devices and components with ‘flat optics’ by utilizing strong interactions between light and two-dimensional structured materials to control light at will. The discovery of this phase-transition material and the successful integration of it into a flat device architecture are a major leap forward to realizing active flat optical devices not only with enhanced performance from the devices we are using today, but with completely new functionalities.”
Yu’s team included Ramanathan, his Harvard PhD student You Zhou, and his Purdue postdoctoral fellow Zhen Zhang, who synthesized the phase-transition material and did some of the phase transition experiments (this work began at Harvard and continued when Ramanathan moved to Purdue); Drexel University Materials Science Professor Christopher Li, PhD student Hao Qi, and research scientist Qiwei Pan, who helped make solid-state devices by integrating SmNiO3 with novel solid polymer electrolytes; and Brookhaven National Laboratory staff scientists Ming Lu and Aaron Stein, who helped device nanofabrication. Yuan Yang, Assistant Professor of Materials Science and Engineering in the Department of Applied Physics and Applied Mathematics at Columbia Engineering, was consulted during the progress of this research.
The Latest on: Intelligent coatings
[google_news title=”” keyword=”Intelligent coatings” num_posts=”10″ blurb_length=”0″ show_thumb=”left”]
via Google News
The Latest on: Intelligent coatings
- Protective Coatings Market Projected to Reach $56.28 billion by 2030 - Exclusive Report by 360iResearchon May 2, 2024 at 7:33 pm
These coatings defend against corrosion for metal structures such ... that rely on our expertise in compiling data in niche markets. Our meta-insights are intelligent, impactful and infinite, and ...
- Foreign firms ride nation's big changeson May 2, 2024 at 4:33 pm
Driven by an automobile production boom in China, Nipsea Group, the Singapore-headquartered paints and coatings manufacturer, will start a new plant, built with an investment of 960 million yuan, in ...
- Konica Minolta Celebrates Customer FSEA Award Winson May 2, 2024 at 6:45 am
Print Panther Direct Honored with Best of Show for Digital Extreme Guide 4 Photo1 April 10, 2024 - Dallas, Texas - Christine Yardley, President, Print Panther Direct accepts her Best of Show award ...
- iPhone 16: All the rumours to know as images are allegedly leakedon May 1, 2024 at 2:53 am
And if the rumours are true, we could be about to see the most artificially intelligent iPhone ever ... Naver blog that Apple is currently testing an anti-reflective optical coating for the cameras on ...
- Amazon crushes it with $179 AirPods Pro 2, $299 Apple Watch Series 9 dealson April 30, 2024 at 8:38 am
Amazon has issued fresh price cuts on Apple AirPods Pro 2 with USB-C and Apple Watch styles, delivering the cheapest prices of the year.
- Packaging Coatings Market Booming to $9.2 Billion by 2034 Fueled by Urbanization and Sustainability | Future Market Insights, Inc.on April 30, 2024 at 3:56 am
The global packaging coating market will reach a valuation of US$ 5.4 billion in 2024, attributed to factors such as urbanization as well as lifestyles. The trend is set to create new opportunities ...
- Introducing Beats Solo Buds: Looks Tiny, Sounds Hugeon April 30, 2024 at 2:59 am
Leveraging upgraded beam-forming microphones and an intelligent noise-learning algorithm ... Breakdown of U.S. retail packaging by weight. Adhesives, inks, and coatings are excluded from our ...
- Taiwan's MIRDC Triumphs Again: One Silver and Two Bronze in Edison Awardson April 28, 2024 at 5:00 pm
At the 2024 Edison Awards, held on April 18th in Florida, the Metal Industries Research & Development Centre (MIRDC), a unit under the aegis of Taiwan's Ministry of Economic Affairs, was once again ...
- Global Meat Interleaving Paper Market Poised for Growth: Expected to Reach US$303.6 Million by 2034on April 25, 2024 at 8:04 am
The Global meat interleaving paper marketis expected to be worth US$ 205.1 million in 2024. By 2034, the market is anticipated to be valued at US$ ...
via Bing News